CBSE Class 12 Physics Chapter 12 Atom NCERT Solutions

NCERT Solutions PDF Class 12 PDF

CBSE Class 12 Physics, Chapter 12: Atom, delves into the fundamental concepts of atomic structure. This chapter explores the historical development of atomic models, comparing Thomson's and Rutherford's theories and explaining the significance of the alpha-particle scattering experiment. Students will understand how this experiment led to the discovery of the atomic nucleus. The solutions also cover the calculation of wavelengths for spectral lines, with a specific focus on the Paschen series and the application of Rydberg's formula. These explanations aim to clarify complex ideas, offer clear problem-solving methods, and support students in their preparation for the CBSE Class 12 Physics exams by providing a solid understanding of atomic structure and spectral analysis.

Quick info

BoardCBSE
ClassClass 12
SubjectPhysics
Session2026
LanguageEnglish
TypeNCERT Solutions
ChapterChapter 12: Atom - NCERT Exercises Solutions

Chapter summary

This chapter's NCERT Solutions for Class 12 Physics focus on atomic models and spectral lines. It covers the comparison between Thomson's and Rutherford's models, the significance of the alpha-particle scattering experiment, and the calculation of spectral line wavelengths, particularly for the Paschen series using Rydberg's formula. The solutions offer clear explanations and detailed steps for solving related problems, reinforcing students' understanding of atomic structure and quantum phenomena.

Learning outcomes

  • Understand and compare Thomson's and Rutherford's atomic models.
  • Analyze the results and implications of the alpha-particle scattering experiment.
  • Apply Rydberg's formula to calculate wavelengths of spectral lines.
  • Determine the shortest wavelength in the Paschen series.
  • Differentiate between stable and unstable electron equilibrium in atomic models.

Topics covered

Paper topics

  • Thomson's Atomic Model
  • Rutherford's Atomic Model
  • Alpha-particle Scattering Experiment
  • Nuclear Model of the Atom
  • Atomic Nucleus
  • Electron Equilibrium
  • Spectral Lines
  • Paschen Series
  • Rydberg's Formula
  • Wavelength Calculation

Important topics

  • Comparison of Thomson's and Rutherford's models
  • Significance of the alpha-particle scattering experiment
  • Rydberg's formula and its application
  • Shortest wavelength in spectral series

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Questions and Solutions

Question 12.1

Choose the correct alternative from the clues given at the end of each statement:
  1. The size of the atom in Thomson's model is ______ the atomic size in Rutherford's model. (much greater than/no different from/much less than.)
  2. In the ground state of ______, electrons are in stable equilibrium, while in ______, electrons always experience a net force. (Thomson's model/ Rutherford's model.)
  3. A classical atom based on ______ is doomed to collapse. (Thomson's model/ Rutherford's model.)
  4. An atom has a nearly continuous mass distribution in ______ but has a highly non-uniform mass distribution in ______. (Thomson's model/ Rutherford's model.)
  5. The positively charged part of the atom possesses most of the mass in ________. (Rutherford's model/both the models.)
Solution:
  1. The sizes of the atoms in Thomson's model and Rutherford's model are generally considered to be of the same order of magnitude, approximately 10^{-10} m. Therefore, the size is no different from.
  2. In Thomson's model, electrons are embedded in a sphere of uniform positive charge, leading to a stable equilibrium. In Rutherford's model, electrons orbit the nucleus and are expected to radiate energy, experiencing a net force towards the nucleus. Thus, in the ground state of Thomson's model, electrons are in stable equilibrium, while in Rutherford's model, electrons always experience a net force.
  3. According to classical electromagnetism, an accelerating charged particle (like an electron orbiting a nucleus) should continuously radiate energy and spiral into the nucleus. This leads to the collapse of the atom. Therefore, a classical atom based on Rutherford's model is doomed to collapse.
  4. In Thomson's model, the positive charge and mass are assumed to be uniformly distributed throughout the atom's volume. In Rutherford's model, the mass and positive charge are concentrated in a tiny nucleus, making the mass distribution highly non-uniform.
  5. In both Thomson's model (where the positive charge is spread out) and Rutherford's model (where the positive charge is concentrated in the nucleus), the positively charged part of the atom possesses most of the mass. Thus, the answer is both the models.

Question 12.2

Suppose you are given a chance to repeat the alpha-particle scattering experiment using a thin sheet of solid hydrogen in place of the gold foil. (Hydrogen is a solid at temperatures below 14 K.) What results do you expect?
Solution:

If the alpha-particle scattering experiment were repeated using a thin sheet of solid hydrogen instead of a gold foil, the results would be significantly different. The alpha particles used in the experiment have a mass approximately 4 atomic mass units (amu) and are positively charged. Gold has a much larger atomic mass (approximately 197 amu).

Hydrogen, on the other hand, has the smallest atomic mass, with its nucleus (a single proton) having a mass of approximately 1 amu. When an alpha particle (mass \approx 4 amu) collides with a hydrogen nucleus (mass \approx 1 amu), the alpha particle is much heavier than the target nucleus.

In such a collision, the alpha particle would transfer only a small amount of momentum and energy to the much lighter hydrogen nucleus. Consequently, the deflection angles of the alpha particles would be very small. It would be highly unlikely for an alpha particle to be scattered backward, as observed with the gold foil, because the heavier alpha particle would not be significantly repelled or deflected by the much lighter proton.

Therefore, we would expect very few, if any, large-angle deflections, and certainly no backscattering, if solid hydrogen were used as the target material.

Question 12.3

What is the shortest wavelength present in the Paschen series of spectral lines?
Solution:

The Paschen series in the hydrogen spectrum corresponds to electron transitions from higher energy levels to the principal quantum level n_1 = 3. The wavelength (\lambda) of the emitted spectral line is given by the Rydberg formula:

\frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right)

where R is the Rydberg constant (R \approx 1.097 \times 10^7 \text{ m}^{-1}), n_1 is the lower energy level, and n_2 is the upper energy level (n_2 > n_1).

For the Paschen series, n_1 = 3. The shortest wavelength occurs when the energy difference between the levels is maximum. This happens for the transition from the highest possible energy level (approaching infinity, n_2 = \infty) to the lowest level of the series (n_1 = 3).

Substituting these values into the Rydberg formula:

\frac{1}{\lambda_{min}} = R \left( \frac{1}{3^2} - \frac{1}{\infty^2} \right)

\frac{1}{\lambda_{min}} = R \left( \frac{1}{9} - 0 \right) = \frac{R}{9}

Now, we can calculate the shortest wavelength:

\lambda_{min} = \frac{9}{R}

Using the value of the Rydberg constant R \approx 1.097 \times 10^7 \text{ m}^{-1}:

\lambda_{min} = \frac{9}{1.097 \times 10^7 \text{ m}^{-1}} \approx 8.204 \times 10^{-7} \text{ m}

Converting this to nanometers (1 nm = 10^{-9} m):

\lambda_{min} \approx 8.204 \times 10^{-7} \text{ m} \times \frac{10^9 \text{ nm}}{1 \text{ m}} \approx 820.4 \text{ nm}

The shortest wavelength present in the Paschen series of spectral lines is approximately 820.4 nm.

Common mistakes

  • Confusing the characteristics of Thomson's and Rutherford's atomic models.
  • Incorrectly applying the conditions for stable equilibrium of electrons.
  • Errors in calculating wavelengths using Rydberg's formula, especially with series limits.
  • Misinterpreting the effect of target nucleus mass in scattering experiments.

Revision tips

  • Create a comparison table for Thomson's and Rutherford's models, highlighting key differences.
  • Review the alpha-particle scattering experiment setup and its conclusions.
  • Practice calculating wavelengths for different spectral series using Rydberg's formula.
  • Focus on understanding the physical meaning behind the mathematical formulas.

Practice MCQs

Q1. In Thomson's model, where are the electrons located?

Q2. What is the primary conclusion from Rutherford's alpha-particle scattering experiment?

Q3. In Rutherford's model, why are electrons expected to spiral into the nucleus?

Q4. The Paschen series of spectral lines corresponds to electron transitions ending at which energy level?

Q5. What happens to the wavelength of spectral lines as the upper energy level (n2) increases for a given lower level (n1)?

Frequently asked questions

What are the main differences between Thomson's and Rutherford's atomic models?

Thomson's model proposed a uniform sphere of positive charge with electrons embedded in it, suggesting continuous mass distribution. Rutherford's model, based on the alpha-scattering experiment, proposed a small, dense, positively charged nucleus containing most of the atom's mass, with electrons orbiting it, leading to a non-uniform mass distribution and potential instability.

Why is the alpha-particle scattering experiment important?

This experiment was crucial as it led to the discovery of the atomic nucleus. The observation that some alpha particles were deflected at large angles indicated that the positive charge and mass of the atom are concentrated in a very small region, contradicting earlier models.

What is the Paschen series in atomic spectra?

The Paschen series refers to the set of spectral lines emitted when an electron in a hydrogen atom transitions from a higher energy level (n > 3) down to the second excited state, which is the energy level with principal quantum number n = 3.

How is the shortest wavelength in a spectral series calculated?

The shortest wavelength corresponds to the transition from the highest possible energy level (approaching infinity, n2 = ∞) to the lowest energy level of that series (n1). This is calculated using Rydberg's formula by setting n2 = ∞.

Can Rutherford's model explain the stability of an atom?

No, Rutherford's model, based on classical physics, predicted that orbiting electrons would continuously radiate energy and spiral into the nucleus, causing the atom to collapse. This instability could not be explained by his model.

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